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Friday, February 24, 2012

Le Chatelier's Principle

Good day!
I hope this post will clarify any problems you may still have with Le Chatelier's Principle, whether it's simply remembering the different effects of various changes, or something else.


I like to think of this principle like sand in a sand box:


If you add sand (more product in this case), the sand will be forced to slide down to maintain a horizontal-like equilibrium. Removing temperature will also cause the same reaction.














But let's say we have another situation:











If you add sand (more product and heat in this case), the sand will be forced to slide down towards the product side in order to maintain a horizontal-like equilibrium.









Notice pressure/volume was not mentioned (because this equilibrium equation has an equal amount of moles on each side (1 + 1 and 2)). It is easy to remember that when pressure is increased or volume is decreased (inversely proportional!), the side with the lower amount of moles is favored.



2 comments:

  1. Hi Joey...

    I love the visuals that you have created and the connection between increasing concentration and adding more sand. Brilliant!

    I have just have one correction to make: In the first example, decreasing the temp will cause a shift to the right, not left (since the system is trying to regenerate some of the heat energy that is lost).

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    Replies
    1. Why thank-you! :D
      Oh whoopsies! Thanks for the correction. I'll get to it A.S.A.P.

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